Biosynthetic isotope fractionation negligibly impacts biomarker 14C ages

نویسندگان

چکیده

Radiocarbon (14C) ages of acetogenic lipid biomarkers such as n-alkanes represent a powerful tool to track carbon-cycle turnover times in range environments including soils, fluvially exported sediments, and marine sediments. However, the fidelity this approach requires that biomarker 14C accurately reflect time has passed since biosynthesis are not complicated by issues isotope fractionation. Reported thus always corrected for mass-dependent fractionation using 14C/13C mass law, b, 2.0. anomalous deviations from dependence could theoretically lead biases measured ages, particularly compounds lipids undergo large 13C fractionations. Here, I test possibility estimating kinetic equilibrium laws various processes involved simple approximations more robust computational chemistry methods. find b values 1.890 1.995 several chain elongation steps 1.856 1.880, consistent with previous results other chemical biological processes. In contrast, complex reaction networks may expressed values, but only when net ln(13α)→0. Combined, these imply maximum age offsets due biosynthetic ~20 40 yr. Biomarker therefore can be confidently interpreted times.

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ژورنال

عنوان ژورنال: Organic Geochemistry

سال: 2021

ISSN: ['1873-5290', '0146-6380']

DOI: https://doi.org/10.1016/j.orggeochem.2021.104267